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In the case of the T-structure, the most convenient orientation has the fragment in the xy plane with the symmetry axis aligned with the x axis The valence orbitals, in ascending order, are dxz b1 , dyz a2 , dxy b2 , nz 2 a1 , nx 2 y 2 a1 , and pz b1 The standard orientation of the trigonal planar structure has the molecule in the xy plane and the C3 axis coinciding with the z axis It is derived from the T-structure by movement of the ligands away from the y axis The resulting valence orbitals and correspondence of the energy levels is shown in Figure 134.

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Color: Will the file be color separated or composite If separations are to be printed, you must make certain all identified colors are named properly in the host document. Often an option is in a Print dialog box to specify whether the file will be separated. As you view the color list, verifying all colors appearing are those you specified in the document is imperative. If a spot color is in the current document, the color won t print unless it is an identified color in the Print dialog box. In as much as you may view preseparated colors to determine if they will be printed properly, you should always send a composite color PDF file to an imaging center and let them do the separations. If you want to be certain of proper printing, you can print separations as PostScript files to disk, distill the files, and view them in an Acrobat viewer. Each of the separated pages will be included in one PDF file so that you can check knockouts, overprints, and colors. Use a separated file to preview the results only, then go back and create a composite PDF to send off to your service center.

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Two of the T-shaped fragment orbitals are signi cantly a ected by the change in geometry, namely the dxy b2 orbital, which su ers a strongly repulsive interaction and rises in energy, and the nx 2 y 2 a1 orbital, which obtains a relief in repulsion and moves to lower energy The result is that the quasidegenerate set of three lowest orbitals is broken apart, leaving only two orbitals H at low energy The valence orbitals, in ascending order, are dxzY dyz e HH , nz 2 a2 , 2 2 H HH nxyY nx y e , and pz a2 Movement of all three ligands of the D3h structure symmetrically out of the plane leads to the pyramidal C3v structure All valence orbitals are a ected by the geometry change The dxzY dyz e HH set can interact with the ligands and are raised in energy.

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H Repulsion is reduced signi cantly in nz 2 a1 and somewhat in the nxyY nx 2 y 2 e H HH set, and these move to lower energy in a corresponding fashion The npz a2 orbital rises In ascending order, the six valence orbitals of the trigonal pyramidal structure are dxzY dyz e, nz 2 a1 , nxyY nx 2 y 2 e, and npz a1 A tricoordinated metal is highly unsaturated Relatively stable fragments occur as follows: 16e s 2 d 8 , structure C3v , eg, Ni(C2 H4 )3 ; 12e s 2 d 4 , structure C2v , eg, HFe(CO)CH3 ; and 10e s 2 d 2 , structure D3h , eg, Ti(NH3 )3 The 10e and 12e structures occur only in the case of the early transition metals, which have the highest energy valence orbitals.

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By the same token, late transition metals can only support higher valence occupancies if they are in high formal oxidation states since the high central positive charge lowers the energy of the higher valence orbitals FIVE VALENCE ORBITALS OF TETRACOORDINATED METAL Three distinct structural types are available for a tetracoordinated fragment: a square planar structure of D4h symmetry, a nonplanar square pyramid with C4v symmetry, a nonplanar structure with C2v symmetry (which would result from the removal of two cis ligands from an octahedral ML6 ), and the tetrahedral structure of symmetry Td These are shown in Figure 135 in the standard orientation The orbitals of the D4h structure.

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